黄浦江下游吴淞口站低潮位重现期研究

黄浦江为感潮河流,低潮位重现期的确定对黄浦江航道的设计具有重要意义。为了准确估计黄浦江低潮位的重现期,以黄浦江下游吴淞口站年最低潮位序列为例,在对样本进行三性审查的基础上,分别采用传统的数理统计方法和时变矩方法进行水文频率分析。结果表明:吴淞口站年最低潮位序列在1996年发生了变异;还现修正后的序列服从位置参数线性时变的GEV模型,低潮位存在缓慢的上升趋势;一致性条件下百年一遇低潮位约为0.261 m,在非一致性条件下其重现期增大为150 a。非一致性条件下的重现期增大说明黄浦江现有的航道设计标准偏安全,航道通航保证率提高。     

Optical properties and conductivity of PEDOT:PSS films treated by polyethylenimine solution for organic solar cells

We report on conductivity and optical property of three different types of poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) films [pristine PH1000 film (PH1000-p), with 5 wt.% ethylene glycol additive (PH1000-EG) and with sulfuric acid post-treatment (PH1000-SA)] before and after polyethylenimine (PEI) treatment. The PEI is found to decrease the conductivity of all the PEDOT:PSS films. The processing solvent of 2-methoxyethanol is found to significantly enhance the conductivity of PH1000-p from 1.1 up to 744 S/cm while the processing solvent of isopropanol or water does not change the conductivity of PH1000-p much. As for the optical properties, the PEI treatment slightly changes the transmittance and reflectance of PH1000-p and PH1000-EG films, while the PEI leads to an substantial increase of the absorptance in the spectral region of 400–1100 nm of the PH1000-SA films. Though the optical property and conductivity of the three different types of PEDOT:PSS films vary with the PEI treatment, the treated PEDOT:PSS films exhibit similar low work function. We demonstrate solar cells with a simple device structure of glass/low-WF PEDOT:PSS/P3HT:ICBA/high-WF PEDOT:PSS cells that exhibit good performance with open-circuit voltage of 0.82 V and fill factor up to 0.62 under 100 mW/cm² white light illumination.     

In-situ modification of PEDOT:PSS work function using alkyl alcohols as secondary processing solvents and their impact on merocyanine based bulk heterojunction solar cells

The influence of a series of alkyl alcohols on the work function of PEDOT:PSS thin films is systematically investigated by Kelvin probe measurements. We show that the PEDOT:PSS work function can be increased stepwise from 5.2 eV for pristine PEDOT:PSS to 5.61 eV using either alcohols with different alkyl chain length or varying the amount of alcohol in mixtures with chlorobenzene. Moreover, we demonstrate the effect of work function modification on merocyanine based bulk heterojunction solar cells, resulting in improved values for the open-circuit voltage comparable to those obtained with high work function MoO₃. Thus, the processing method presented herein can potentially serve as a simple, alternative route to adjustable and high work function electrodes while maintaining processability from solution.     

浅谈蒲汇塘排水系统改造工程设计

上海蒲汇塘排水系统改造工程属上海市中心城区低标准排水系统改造工程,为提高雨水排水标准,解决严 重暴雨积水点,在进行充分调查的基础上,调整了排水系统管网布局和泵站规模。同时结合周围城市轨道交通建设,优 化系统总管及泵站工程设计,为今后低标准排水系统改造工程实施提供可参考的实例。     

次氯酸钠氧化脱除河水低浓度氨氮研究

通过静态试验,分别研究了河水中氯与氨氮的质量比、反应时间、pH值及初始NH3-N浓度对NH3-N去除效果的影响。试验结果表明,对于不同天气情况下的水样,氯与氨氮的质量比(以Cl2∶N计)为10∶1~12∶1时,NH3-N浓度可降低至0.5 mg/L以下;反应时间20 min时,NH3-N浓度可达到0.3 mg/L,工程应用中可将反应时间延长至30 min;pH对NH3-N去除效果没有明显影响,一般不需要调节河水pH;在pH值为8.0,氯与氨氮的质量比为12∶1,初始NH3-N浓度为0.5~3.0 mg/L时,反应后NH3-N浓度均<0.3 mg/L。     

NO reduction using low-temperature SCR assisted by a DBD method

This paper discusses the removal of nitric oxide(NO) with low-temperature selective catalytic reduction driven by a dielectric barrier discharge with ammonia(NH_3) as a reductant. We explored the effects of NH_3, O_2, temperature and water under different applied voltage on NO removal at atmospheric pressure. The results showed that when the gas concentration ration of NH_3/NO was 0.23–0.67, the NO removal efficiency and the energy consumption was acceptable. The NO removal efficiency reached 84% under an applied voltage of 7 kV, 400 ppm NO and 90 ppm NH_3 at a temperature of 150 ℃. Water vapor had a negative effect because NO formation reactions were strengthened and NH_3 was oxidized directly rather than reduced NO molecules. The outlet gas components were observed via Fourier transform infrared spectroscopy for revealing the decomposition process and mechanism.     

Mapping Sea Level Rise Behavior in an Estuarine Delta System: A Case Study along the Shanghai Coast

Sea level rise (SLR) is a major projected threat of climate change that is expected to affect developing coastal cities located in estuarine delta regions. Shanghai is one such city, being located in the Yangtze River Delta (YRD). It is difficult, however, for decision-makers to implement adaptation due to the uncertain causes, magnitudes, and timings of SLR behaviors. This paper attempts to map the causes and magnitudes of SLR behaviors on a decadal scale. We analyze the tidal level records from 11 tidal gauge stations and the corresponding bathymetry measurements around these stations since 1921. We identify three new SLR behaviors along the Shanghai coast due to anthropogenic geomorphologic changes (AGCs), besides the well-known eustatic sea level rise (ESLR), tectonic subsidence (TS), and urban land subsidence (ULS). The first new behavior is regional sea level rise (RSLR), which occurs as a result of land reclamation and deep waterway regulation. The second is regional sea level fall (RSLF), which occurs because the channel bed is eroded due to sediment supply decline in the river catchment. The last SLR behavior is local tidal datum rise (LTDR). Thus, we project that the magnitude of SLR for the Shanghai coast ranges from 10 cm to 16 cm from 2011 to 2030. Clarifying SLR behaviors is important to aid local decision-makers in planning structural and non-structural measures to combat escalating flood damage costs in an estuarine delta system; this field is full of future challenges.     

Intelligent release of cinnamon oil from engineered proteoliposome via stimulation of Bacillus cereus protease

Inspired by the hydrolysis of casein by protease, a new approach to deliver antimicrobials against bacterial infections was developed in this study. As a natural antibacterial agent, cinnamon oil was encapsulated into engineered liposomes inlaid with casein. The average particle size of proteoliposomes was 615.0 nm and their entrapment efficiency (EE) was 40.0%. In this work, Bacillus cereus (B. cereus) was chosen as model bacterium. The controlled release of liposome-encapsulated cinnamon oil was realized via bacterial protease secreted from B. cereus. As a result, 99.99% of the bacteria could be efficiently inhibited in rice and wheat flour.     

��˿�������ƶ�����Ӱ������̽��

 整绳破断力已成为钢丝绳检验的主要参数,根据GB/T8358－2006《钢丝绳破断拉神试验方法》对影响试验结果的因素进行了探讨,发现选择合适的夹持方法以及试验仪器能有效地提高试验成功率。     

采用伪谱法的再入飞行器最优反馈制导方法

将伪谱最优反馈控制理论应用于再入飞行器制导研究,使用伪谱法进行在线轨道重构,实时反馈更新当前轨道控制量迎角和倾斜角,达到实时最优反馈制导的目的,并采用无量纲化、弹性约束和自适应反馈更新等策略保证算法的实时性。再入飞行仿真表明,轨道重构可以满足实时性要求,阵风干扰下飞行器能达到所要求的终端约束条件,并且制导指令不会出现增加控制难度的抖动现象。